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CaCl2 titrant is added in predetermined time intervals and recorded in a notebook. The titrant raises the supersaturation of aragonite in solution. The level of supersaturation required to induce a whiting event is related to the presence or absence of particles that act as nucleation sites.
Saturation state ( The data set at the left shows: A. Amount and rate of titrant addition to induce nucleation; and B. The pH response to titrant addition before whiting and to aragonite growth after whiting. |