> Is there a way of using PhreeqcI to model the interaction of a relatively low solids brine containing both CO2 and H2S, plus some glycol? I am interested in modeling the behavior of such a brine vs. temperature and pressure, to determine the extent of degradation of the glycol. I'm not sure what you need. PHREEQC is not good with high ionic strength waters, say 1 molal and greater. On the other hand, I'm not sure what part of the thermodynamics you need. If it is just solubility of gases, it might be adequate; it has a linear log activity coefficient expression for uncharged species. Charged species will get more unreliable the higher the ionic strength. PHREEQC has no explicit pressure dependence in the aqueous model, but it is possible to specify partial pressures of ideal gases. I'd be reluctant to push things past a few atmospheres total pressure. You would have to define a new "Element" glycol and any dissociation/complexation that are pertinent. If you are trying to do all this a priori, I suspect you can't do it. If you are trying to model some experiments, you may be able to use some of the features of PHREEQC. David David Parkhurst (dlpark@xxxxxxxx) U.S. Geological Survey Box 25046, MS 413 Denver Federal Center Denver, CO 80225 Project web page: https://wwwbrr.cr.usgs.gov/projects/GWC_coupled
Please note that some U.S. Geological Survey (USGS) information accessed through this page may be preliminary in nature and presented prior to final review and approval by the Director of the USGS. This information is provided with the understanding that it is not guaranteed to be correct or complete and conclusions drawn from such information are the sole responsibility of the user.
Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by the U.S. Government.
The URL of this page is:
Last modified: $Date: 2005-09-13 21:04:21 -0600 (Tue, 13 Sep 2005) $
Visitor number 2437 since Jan 22, 1998.